Dr. Klaus Kerpen

Fakultät für Chemie
Instrumentelle Analytische Chemie
Universitätsstr. 5, S05 V02 E38
45141 Essen

Tel: +49(0)201 183-6787
Fax: +49(0)201 183-6773
email: klaus.kerpen@uni-due.de

Current project: „Schnelle Vor-Ort-Analytik zur Detektion von Pestiziden in Wässern mittels 2D-Ionenmobilitätsspektrometrie (Hydro-2D-DMS)“

Publications:

V. Bachler, F.-W. Grevels, K. Kerpen, G. Olbrich und K. Schaffner. A Novel Facet of Carbonyliron-Diene Photochemistry: The 4-s-trans Isomer of the Classical Fe(CO)3(4-s-cis-1,3-butadiene) Discovered by Time-Resolved IR Spectroscopy and Theoretically Examined by Density Functional Methods. Organometallics 2003, 22, 1696-1711.

F.-W. Grevels, K. Kerpen, W. E. Klotzbücher, K. Schaffner, R. Goddard, B. Weimann, C. Kayran, S. Özkar. Dissociative CO Photosubstitution in M(CO)4(1,4-diazabutadiene) Complexes (M = W, Mo) by an Olefin Affording Novel fac-M(CO)3(1,4-diazabutadiene)(2-olefin) Derivatives. Organometallics 2001, 20, 4775-4792.

H. Hennig, K. Ritter, A. K. Chibisov, H. Görner, F.-W. Grevels, K. Kerpen, K. Schaffner. Comparative time-resolved IR and UV spectroscopic study of monophosphine and diphosphine platinum(II) azido complexes. Inorg. Chim. Acta 1998, 271, 160-166.

F.-W. Grevels, K. Kerpen, W. E. Klotzbücher, R. E. D. McClung, G. Russell, M. Viotte, K. Schaffner. The Very Low Barrier of CO Site Exchange in Tricarbonyl(4-1,5-cyclooctadiene)iron: Picosecond Kinetics in Solution Investigated by Line Shape Simulation of the (CO) IR Bands and Complementary Evidence from the Course of 13CO Incorporation in a Low-Temperature Matrix. J. Am. Chem. Soc. 1998, 120, 10423-10433.