Publications 2022

Publications 2022

[299] J. Krüger, C. Wölper, S. Schulz*​Bild1

Role of group 13 metals on the electronic properties of L(X)M-substituted Pnictinidenes
Organometallics 2022, 41, 3788.

This paper was highlighted as Inside Cover!
Organometallics 2022, 41, Issue 23.      

[298] M. K. Sharma, S. Chabbra, C. Wölper, M. Weinert, E. J. Reijerse, A. Schnegg, S. Schulz*​frontcover301

Modulating the Frontier Orbitals of L(X)Ga-Substituted Diphosphenes [L(X)GaP]2 (X = Cl, Br) and their Facile Oxidation to Radical Cations
Chem. Sci. 2022, 13, 12643.
DOI: 10.1039/D2SC04207J

Inside Front Cover
Chem. Sci. 2022, 13, 12592
DOI: 10.1039/D2SC90227C

[297] C. Stienen, J. Grahl, C. Wölper, S. Schulz, G. Bendt
Fluorinated β-diketonate complexes M(tfac)2(TMEDA) (M = Fe, Ni, Cu, Zn) as precursors for the MOCVD growth of metal and metal oxide thin films
RSC Adv. 2022, 12, 22974-22983.
DOI: 10.1039/D2RA01338J

[296] S. Ghosh, Y. Schulte, C. Wölper, A. Tjaberings, A. H. Gröschel, G. Haberhauer, S. Schulz*
Cooperative Effect in Binuclear Zinc Catalysts in the ROP of Lactide
Organometallics 2022, 41, 2698.
DOI: 10.1021/acs.organomet.2c00333

[295] A. Bücker, C. Wölper, G. Haberhauer, S. Schulz*
Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle
Chem. Commun. 2022, 58, 9758.
DOI: 10.1039/D2CC03561H

[294] J. Haak, J. Krüger, N. V. Abrosimov, C. Helling, S. Schulz, G. E. Cutsail III
X-band Parallel-Mode and Multifrequency Electron Paramagnetic Resonance Spectroscopy of S = 1/2 Bismuth Centers
Inorg. Chem. 2022, 61, 11173.
See also: ChemRxiv. Cambridge: Cambridge Open Engage; 2022; This content is a preprint and has not been peer-reviewed.
DOI: 10.26434/chemrxiv-2022-wp6l3

[293] J. Schoening, A. Gehlhaar, C. Wölper, S. Schulz*
Selective [2+1+1] Fragmentation of P4 by heteroleptic MetallasilylenesChem202201982-toc-0001-m

Chem. Eur. J. 2022, 28, e202201031.
DOI: 10.102/chem.202201031

This paper was highlighted as HOT paper!

Front Cover
Chem. Eur. J. 2022, 28, e202201982.
DOI: 10/1002/chem.202201982

[292] S. Schulz,*
Group 15/16 single-source precursors for energy materials (chapter 10)
Nanomaterials via Single-Source Precursors - Synthesis, Processing and Applications, Ed. A. W. Apblett, A. R. Barron, A. F. Hepp, Elsevier Inc. 2022, 313-356.
DOI: 10.1016/B978-0-12-820340-8.00010-1

[291] C. Färber, P. Stegner, U. Zenneck, C. Knüpfer, G. Bendt, S. Schulz, S. Harder*
Teaming up main group metals with metallic iron to boost hydrogenation catalysis
Nat. Commun. 2022, 13, 3210.
DOI: 10.1038/s41467-022-30840-4

[290] E. Glöckler, S. Ghosh, C. Wölper, D. Coban, A. H. Gröschel, S. Schulz*
Binuclear ketodiiminate magnesium complexes for the ROP of cyclic L-Lactide and ε-Caprolactone
Polyhedron 2022, 222, 115918.
DOI: 10.1016/j.poly.2022.115918d2cc90207a

[289] A. Gehlhaar, H. M. Weinert, C. Wölper, N. Semleit, G. Haberhauer,* S. Schulz*
Bisstibane−Distibane conversion via consecutive single-electron oxidation and reduction reaction
Chem. Commun. 2022, 58, 6682.
DOI: 10.1039/D2CC01986H

Front Cover

Chem. Commun. 2022, 58, 6673.
DOI: 10.1039/D2CC90207A

[288] J. Schoening, C. Ganesamoorthy, C. Wölper, E. Solel, P. R. Schreiner, S. Schulz*
Synthesis, electronic nature, and reactivity of selected silylene carbonyl complexes
Dalton Transactions 2022, 51, 8249.
DOI: 10.1039/D2DT01335E

[287] B. Li, B. L. Geoghegan, H. M. Weinert, C. Wölper, G. E. Cutsail III, S. Schulz*
Synthesis and redox activity of carbene-coordinated group 13 metal radicals
Chem. Commun. 2022, 58, 4372.
DOI: 10.1039/D2CC00216G

[286] J. Krüger, J. Haak, C. Wölper, G. E. Cutsail III,* G. Haberhauer,* S. Schulz*
Single Electron Oxidation of Carbene-Coordinated Pnictinidenes Entry into Heteroleptic Radical Cations and Metalloid Clusters
Inorg. Chem. 2022, 61, 5878.
DOI: 10.1021/acs.inorgchem.2c00249

[285] C. Helling, J. Haak, C. Wölper, G. Cutsail III, S. Schulz*
Sequential Reduction of a Borylstibane to an Electronically Non-Symmetric Diboryldistibene Radical Anion
Inorg. Chem. 2022, 61, 5124.
DOI: 10.1021/acs.inorgchem.2c00251

[284]  H. M. Weinert, C. Wölper, Y. Schulte, S. Schulz*
Synthesis of Distibiranes and Azadistibiranes by Cycloaddition Reactions of Distibenes with Diazomethanes and Azides
Chem. Sci. 2022, 13, 3775.
DOI: 10.1039/D2SC00314G 

[283] A. Gehlhaar, E. Schiavo, C. Wölper, Y. Schulte, A. A. Auer,* S. Schulz*D2DT90054H

Comparing London Dispersion Pnictogen-π Interactions in Naphthyl-substituted Dipnictanes
Dalton Trans. 2022, 51, 5016.
DOI: 10.1039/D2DT00477A

Front Cover

Dalton Trans. 2022, 51, 4931.
DOI: 10.1039/D2DT90054H

This paper was highlighted as HOT paper!

[282] M. K. Sharma, P. Dhawan, C. Helling, C. Wölper, S. Schulz*
Bis-phosphaketenes LM(PCO)2 (M = Ga, In): A new class of reactive group 13 metal–phosphorus compounds
Chem. Eur. J. 2022, 28, e202200444.
DOI: 10.1002/chem.202200444
The article was featured in Chemical Views!

[281] S. Zerebecki, S. Salamon, J. Landers, Y. Yang, Y. Tong, E. Budiyanto, D. Waffel, M. Dreyer, S. Saddeler, T. Kox, S. Kenmoe, E. Spohr, S. Schulz, M. Behrens, M. Muhler, H. Tüysüz, R. K. Campen, H. Wende, S. Reichenberger, S. Barcikowski
Engineering of Cation Occupancy of CoFe2O4 Oxidation Catalysts by Nanosecond, Single-Pulse Laser Excitation in Water
ChemCatChem 2022, 14, e202101785.
DOI: 10.1002/cctc.2021101785

[280] F. van der Vight, S. Schulz, G. Jansen
Effects of Dispersion and Charge -Transfer Interactions on Structures of Heavy Chalcogenide Compounds: A Quantum Chemical Case Study for (Et2Bi)2Te
ChemPlusChem 2022, 87, e202100487.
DOI: 10.1002/cplu.202100487

[279] C. Helling, C. Ganesamoorthy, C. Wölper, S. Schulz*
Geminal C–Cl and Si–Cl Bond Activation of Chloromethanes and Chlorosilanes by Gallanediyl LGa
Dalton Trans. 2022, 51, 2050.
DOI: 10.1039/D1DT04192D  

[278] M. K. Sharma, C. Wölper, S. Schulz*
Selective 1,2 addition of polar X–H bonds to the Ga–P double bond of gallaphosphene L(Cl)GaPGaL
Dalton Trans. 2022, 51, 1612.
DOI: 10.1039/D1DT04299H

[277] J. Krüger, C. Wölper, G. Haberhauer,* S. Schulz*
Switching from Heteronuclear Allyl Cations to Vinyl Cations by Using a Chemical Charge Trap
Inorg. Chem. 2022, 61, 597.
DOI: 10.1021/acs.inorgchem.1c03279

[276] J. Krüger, C. Wölper, A. Auer, S. Schulz*
Formation and Cleavage of a Sb–Sb double bond: From Carbene-Coordinated Distibenes to Stibinidenes
Eur. J. Inorg. Chem. 2022, e202100960.
DOI: 10.1002/ejic.202100960
This paper was highlighted as HOT paper!

[275] S. Ghosh, E. Glöckler, C. Wölper, J. Linders, N. Janoszka, A. H. Gröschel, S. Schulz*
Comparison of the catalytic activity of mono- and multinuclear Ga complexes in the ROCOP of Epoxides and Cyclic Anhydrides
Eur. J. Inorg. Chem. 2022, e202101017.
DOI: 10.1002/ejic.202101017
Part of a joint Special Collection on “Main Group Catalysis”.  

[274] A. Gehlhaar, C. Wölper, F. van der Vight, G. Jansen, S. Schulz*
Noncovalent intra- and intermolecular interactions in peri-substituted pnicta naphthalene and acenaphthalene complexes
Eur. J. Inorg. Chem. 2022, e202100883.
DOI: 10.1002/ejic.202100883